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Luminescence Efficiency of Si/SiO 2 Nanoparticles Produced by Laser Ablation

2019

Photoluminescence properties of Si(core)/SiO 2 (shell) nanoparticles produced by pulsed laser ablation in aqueous solution are investigated with the purpose to highlight the microscopic processes that govern the emission brightness and stability. Time resolved spectra evidence that these systems emit a µs decaying band centered around 1.95 eV, that is associated with the radiative recombination of quantum-confined excitons generated in the Si nanocrystalline core. Both the quantum efficiency and the stability of this emission are strongly dependent on the pH level of the solution, that is changed after the laser ablation is performed. They enhance in acid environment because of the H + pass…

PhotoluminescenceLaser ablationMaterials scienceSi/SiO2 nanoparticles pulsed laser ablation quantum confinement luminescence IR absorption pH dependencebusiness.industry2Surfaces and InterfacesCondensed Matter Physicslaser ablation; pH dependence; photoluminescence; quantum confinement; Si/SiO ; 2; nanoparticlesquantum confinementSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsQuantum dotSio2 nanoparticleslaser ablationMaterials ChemistryPh dependenceOptoelectronicsphotoluminescencenanoparticlespH dependenceElectrical and Electronic EngineeringLuminescencebusinessSi/SiOphysica status solidi (a)
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